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1 article(s) from Endo, Takeshi

Selective formation of a zwitterion adduct and bicarbonate salt in the efficient CO₂ fixation by N-benzyl cyclic guanidine under dry and wet conditions

Yoshiaki Yoshida,
Naoto Aoyagi and
Takeshi Endo

Beilstein J. Org. Chem. 2018, 14, 2204–2211, doi:10.3762/bjoc.14.194

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Scheme 1: Fixation of CO₂ (200 mL/min) by 1 under (a) dry and (b) wet conditions.

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Figure 1: Zwitterion adduct 2 and bicarbonate salt 3 confirmed by elemental analysis.

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Figure 2: ¹³C NMR spectra of (a) 1 observed in DMSO-d₆, (b) 3' prepared with 2 and D₂O observed in D₂O, and (...

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Figure 3: FTIR-ATR spectra of zwitterion adduct 2 and bicarbonate salt 3 expanded at the range of 1500–1800 cm...

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Figure 4: ¹³C-CPMAS NMR spectra of zwitterion adduct 2 and bicarbonate salt 3 expanded at the range of 30–170...

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Figure 5: The optimized geometries of zwitterion adduct 2 and bicarbonate salt 3 estimated by DFT calculation...

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Figure 6: TGA trace of (a) zwitterion adduct 2 and (b) bicarbonate salt 3 observed under N₂ flow (200 mL/min)...

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Scheme 2: Proposal decomposition paths and theoretical weight loss values of (a) zwitterion adduct 2 and (b) ...

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Published 23 Aug 2018

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Selective formation of a zwitterion adduct and bicarbonate salt in the efficient CO2 fixation by N-benzyl cyclic guanidine under dry and wet conditions

Selective formation of a zwitterion adduct and bicarbonate salt in the efficient CO₂ fixation by N-benzyl cyclic guanidine under dry and wet conditions